Atmospheric Environment Research Articles

Analysis of Meteorological Drivers of Taihu Lake Algal Blooms over the Past Two Decades and Development of a VOCs Emission Inventory for Algal Bloom

Cyanobacterial blooms represent a common environmental issue in aquatic systems, and these blooms bring forth numerous hazards, with the generation of volatile organic compounds (VOCs) being one of them. Global climate change has led to alterations in various climatic factors affecting algal growth, indirectly impacting the quantity of VOCs released by algae. With advancements in remote sensing technology, exploration of the spatiotemporal distributions of algae in large water bodies has become feasible. This study focuses on Taihu Lake, characterized by frequent occurrences of cyanobacterial blooms. Utilizing MODIS satellite imagery from 2001 to 2020, we analyzed the spatiotemporal characteristics of cyanobacterial blooms in Taihu Lake and its subregions. Employing the LightGBM machine learning model and the (SHapley Additive exPlanations) SHAP values, we quantitatively analyzed the major meteorological drivers influencing cyanobacterial blooms in each region. VOC-related source spectra and emission intensities from cyanobacteria in Taihu Lake are collected based on the literature review and are used to compile the first inventory of VOC emissions from blue-green algae blooms in Taihu Lake. The results indicate that since the 21st century, the situation of cyanobacterial blooms in Taihu Lake has continued to deteriorate with increasing variability. The relative impact of meteorological factors varies across different regions, but temperature consistently shows the highest sensitivity in all areas. The VOCs released from the algal blooms increase with the proliferation of the blooms, posing a continuous threat to the atmospheric environment of the surrounding cities. This study aims to provide a scientific basis for further improvement of air quality in urban areas adjacent to large lakes.

The Troll Observing Network (TONe): plugging observation holes in Dronning Maud Land, Antarctica

Antarctica and the Southern Ocean play vital roles in the Earth system, exerting significant influence on global atmospheric, cryospheric, and oceanic processes. Understanding the ongoing changes in Antarctica and their broader impact on global dynamics is imperative. Achieving this understanding necessitates dedicated and coordinated observations of environmental parameters in the region. The Troll Observing Network (TONe) is Norway's proactive initiative to the call for sustained, coordinated, complementary, geographically spread, and societally relevant long-term observations from Antarctica. Centered around the Troll Research Station in Dronning Maud Land, a region characterized by limited data availability, TONe constitutes a comprehensive state-of-the-art observatory network, specifically designed for environmental observations for studying and monitoring of the atmosphere, terrestrial, and marine environments. TONe aims to facilitate broad and open access to observational data and shared services to the international research communities as a foundation for acquiring knowledge of societal significance. TONe will, however, be a limited contribution the broader international data gathering effort required to underpin a strengthened understanding of Antarctica in the Earth system. TONE is an important initiative focused on a data sparse region of Antarctica, but has only substantial added value when seen in the context of similar ongoing and future efforts around the continent.

Urban trees' potential for regulatory services in the urban environment: an exploration of carbon sequestration.

Urbanisation has emerged as a formidable challenge for urban policymakers, reaching unparalleled heights and unsettling the ecological equilibrium of the cities. Urban areas now grapple with many issues encompassing climate change, resource depletion, population surges and increased pollution levels. Many planned cities have planted trees and other vegetation within the urban sectors to enhance air quality, mitigate climate effects and provide valuable ecosystem services. This study assessed tree species diversity and their potential for carbon sequestration in Panjab University Campus, Chandigarh. We established 188 plots, each comprising randomly selected quadrats measuring 10 m × 10 m, encompassing areas with varying levels of vegetation, ranging from low to moderate and high density. We used four different allometric equations to estimate tree biomass and carbon stock. Our findings revealed that 92 tree species belong to 72 genera and 35 families, with a total tree density of 975 ha-1. The total CO2 sequestration in form of carbon stock was 18,769.46 Mg C ha-1, with Manilkara hexandra (1239.20 Mg C ha-1), Ficus benghalensis (1072.24 Mg C ha-1), Kigelia pinnata (989.89 Mg C ha-1) and Lagerstroemia floribunda (716.88 Mg C ha-1) being the top contributors. Specifically, the equation of Chave et al. (2005) without tree height yielded the highest biomass and carbon stock estimates than other equations. The present study underscores the vital role of trees on the campus as potent carbon reservoirs meet to maintain an aesthetic sense for biotic components and alleviate rising levels of CO2 in the atmospheric environment. By emphasising the role of urban trees as potent carbon reservoirs, the study underscores the importance of integrating green infrastructure into urban planning strategies. Furthermore, it offers valuable guidance for urban planners. It suggests that strategic tree planting and maintenance can enhance green spaces, regulate temperatures and ultimately support regional and global climate change mitigation goals. Incorporating these findings into urban planning processes can aid policymakers in developing resilient, ecologically sustainable cities worldwide.

Editorial: Crucial air quality, atmospheric environment, and climate change in low- and middle-income countries

Editorial: Crucial air quality, atmospheric environment, and climate change in low- and middle-income countries

Mitigation of Reentry Blackout via Gas Injection in Arc-Heating Facility

Abstract Communication blackouts during atmospheric reentry pose significant challenges to the safety and adaptability of spacecraft missions. 
This phenomenon, caused by the attenuation of electromagnetic waves by the plasma surrounding the spacecraft, disrupts communication with ground stations or orbiting satellites.
Therefore, it is crucial to decrease the plasma density in the vicinity of the spacecraft to ensure an unobstructed electromagnetic wave communication path.
This study proposes a methodology that involves the injection of gas from the vehicle's wall to create an insulating layer near the surface. 
This thin layer maintains lower temperatures and reduced plasma density, enabling electromagnetic wave propagation without attenuation. 
Practical experiments were conducted in an arc-heating facility to simulate atmospheric reentry conditions.
The results of the experiments provided empirical evidence of the effectiveness of the technique in mitigating communication blackout phenomena.
Numerical fluid analysis within the wind tunnel chamber validated the formation of an air film layer near the experimental model owing to the injected gas. 
Schlieren imaging revealed distinctive jet shapes, which corroborated the findings of the numerical analysis. 
The wind tunnel tests that simulated atmospheric reentry environments confirmed the formation of an air film layer through gas injection, which substantiates the reduction in communication blackout.
These results have the potential to improve communication reliability in space transport.

Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry.

Chemical ionization (CI) atmospheric pressure interface mass spectrometry is a unique analytical technique for its low detection limits, softness to preserve molecular information, and selectivity for particular classes of species. Here, we present a fast polarity switching approach for highly sensitive online analysis of a wide range of trace species in complex samples using selective CI chemistries and high-resolution mass spectrometry. It is achieved by successfully coupling a multischeme chemical ionization inlet (MION) and an Orbitrap Fourier transform mass spectrometer. The capability to flexibly combine ionization chemistries from both polarities effectively extends the detectability compared to using only one ionization chemistry, as commonly used positive and negative reagent ions tend to be sensitive to different classes of species. We tested the performance of the MION-Orbitrap using reactive gaseous organic species generated by α-pinene ozonolysis in an environmental chamber and a standard mixture of 71 pesticides. Diethylammonium and nitrate are used as reagent ions in positive and negative polarities. We show that with a mass resolving power of 280,000, the MION-Orbitrap can switch and measure both polarities within 1 min, which is sufficiently fast and stable to follow the temporal evolution of reactive organic species and the thermal desorption profile of pesticides. We detected 23 of the 71 pesticides in the mixture using only nitrate as the reagent ion. Facilitated by polarity switching, we also detected 47 pesticides using diethylammonium, improving the total number of detected species to 59. For reactive organic species generated by α-pinene ozonolysis, we show that combining diethylammonium and nitrate addresses the need to measure oxygenated molecules in atmospheric environments with a wide range of oxidation states. These results indicate that the polarity switching MION-Orbitrap can promisingly serve as a versatile tool for the nontargeted chemical analysis of trace species in various applications.

Accelerated reduction in China's cropland fires against the background of policy enhancement

Cropland fires contribute significantly to the emission of air pollutants, with implications for the atmospheric environment, public health, and climate change. However, the development of cropland fires in response to straw burning policy interventions has not been fully explored. With the Moderate Resolution Imaging Spectroradiometer Collection 6 (MODIS C6) active fire products and China land-cover data (CLCD), counts and fire radiative power (FRP) of cropland fire spots were extracted in China from 2003 to 2022, followed by analyses of their spatiotemporal patterns and evolutionary characteristics at the provincial, regional, national, and grid (0.25° × 0.25°) levels and at monthly to annual scales via trend analysis, kernel density analysis, and geographic distribution analysis. The key findings include: (1) National policies banning straw burning reversed the changes in the quantity and intensity of China's cropland fires in 2013, with the frequency and FRP in 2022 declining by 58% and 62% compared with the 2014 peak. (2) Cropland fires were highly prevalent in Northeast and North China (NEC and NC), with significant regional differences, particularly in spring, summer and autumn. (3) A notable lag effect of burning ban policies was seen in Northeast China (NEC), where the increasing trends of the frequency and intensity of cropland fires were not reversed until 2017, followed by declines in frequency and FRP of 67% and 62%, respectively during 2017–2022. (4) Cropland fires showed an increasing concentration trend but with enormous regional differences, with an increasing trend of a “high-high” concentration pattern in NEC and a decreasing trend in NC. This study contributes to understanding the effectiveness of national policies that ban straw burning and support cropland fire management and policy-making.

SiC-armoured triple-layered superhydrophobic coating with super-robustness and anti-corrosion durability

Continuously enhancing the mechanical stability and durability of superhydrophobic corrosion-resistant materials is a great challenge for researchers. In this paper, we developed a SiC armoured triple-layered superhydrophobic coating with super-robustness on Q235 carbon steel substrates. The triple-layered coating was achieved by sequentially applying an epoxy (EP) resin adhesive layer, a SiC-armored skeleton structure, and a superhydrophobic F-Al2O3@EP layer. The resulting coating demonstrated outstanding non-wetting superhydrophobicity, featuring a static water contact angle (WCA) of 157.7 ± 0.5° and a sliding angle (SA) of 3.7 ± 0.6°. Moreover, the designed triple-layered superhydrophobic coating exhibits ultra-low interfacial adhesion force and demonstrates self-cleaning ability. Its mechanical stability was significantly heightened, enduring more than 2700 sandpaper abrasion cycles, 2200 tape-peeling cycles, and 3000 g sand impact resistance. Additionally, the coating displayed superior corrosion resistance with eight orders of magnitude enhanced charge transfer resistance (Rct), 590 mV positive shift corrosion potential (Ecorr), and six orders of magnitude lower corrosion current density (Icorr) in a 3.5 wt% NaCl solution. Impressively, the SiC armoured triple-layered superhydrophobic coating demonstrated prolonged marine anti-corrosion performance, enduring immersion in a 3.5 wt% NaCl solution for over 1200 h and exposure to the outdoor marine atmospheric environment for more than 3360 h. We believe the development of superhydrophobic materials with high stability and durability contributes to their widespread adoption and multifunctional applications.

Uncovering the evolution of ozone pollution in China: A spatiotemporal characteristics reconstruction from 1980 to 2021

Ozone pollution emerged as a significant environmental concern in China in recent years. Given the enduring impact of anthropogenic activities on the atmosphere, understanding the long-term evolutionary patterns of ozone pollution is crucial for effective pollution mitigation strategies. However, there have been limited studies to reconstruct spatiotemporal continuity ozone concentrations in China since 1980. In this research, monthly and daily MDA8 ozone concentrations from 1980 to 2021 were first estimated by reproducing the numerical relations between ozone pollution and the atmospheric environment based on a machine learning approach. The verification results from temporal, spatial, and sample-based cross-validation methods demonstrated the model performance in simulating MDA8 ozone concentration spatiotemporally, with correlation coefficients (R) ranging from 0.76 to 0.79, mean square error (RMSE) ranging from 22.72 μg·m−3 to 24.28 μg·m−3, and mean absolute error (MAE) ranging from 17.06 μg·m−3 to 18.25 μg·m−3. The evolution of ozone pollution in China can be delineated into two phases, characterized by an increasing trend since 2001, coinciding with significant rises in average annual temperature and hot weather frequency over the past four decades. The 90th percentile of ozone concentration from 2001 to 2021 increased by 1.79% compared to the period from 1980 to 2001. Notably, ozone episodes have expanded beyond summer months, partly due to global warming and frequent extreme climate events, contributing to an annual temperature increase of 0.03 °C. Despite several pollutant emission restrictions since 2013, the ozone pollution in China has persisted due to the increased emissions of VOCs. Spatially, severe ozone pollution hotspots are evident in Xinjiang province, the Jing-Jin-Ji urban agglomeration, and Northeast China, with notable increases observed in Tibet and the Guangdong-Hong Kong-Macao Greater Bay Area over the past six years. Moreover, the influence factors were identified by the average reduction of node impurity calculation. The evolution of ozone pollution was inextricably linked to solar radiation and atmospheric temperature, which played pivotal positive roles in ozone formation. Whilst, there is significant heterogeneity in the effect of meteorological conditions on ozone concentrations due to the disparity between land and oceanic climates.

An increased wax load on the leaves of goji plants (Lycium barbarum) results in increased resistance to powdery mildew

Abstract Background Goji (Lycium barbarum) is an important economic crop that is widely cultivated in Northwest China and is known as superfood. Goji plants are often affected by powdery mildew (Arthrocladiella mougeotii) in the field, resulting in considerable reduction in production and serious economic losses. The long-term reliance on agricultural chemicals to control powdery mildew not only leads to environmental pollution, but also causes excessive residues to accumulate in fruits, endangering human health. The plant epicuticular wax is the first physical barrier between land plants and the atmospheric environment, and plays an important role in the interactions of plants with pathogenic microorganisms. However, the relationship between epicuticular wax and powdery mildew resistance in goji plants is not well understood. Results The leaf epicuticular wax crystals of ‘Ningqi I’ goji were dense and small, and the wax load was 121.74 μg/cm2, which was 3.36 times greater than that of ‘Huangguo’ goji. The ratio of alcohol components in ‘Ningqi I’ goji was 121.18% greater than that in ‘Huangguo’ goji. The incidence rate and disease index of ‘Ningqi I’ goji inoculated with powdery mildew were significantly lower than those inoculated ‘Huangguo’ goji, showing high resistance and moderate susceptibility, respectively. After mechanical wax removal, the disease indices of the two goji varieties increased significantly, indicating extreme susceptibility. Seventeen differential expression genes showing significantly greater expression in ‘Ningqi’ goji leaves than in ‘Huangguo’ goji leaves were enriched in genes involved in fatty acid elongation and the wax biosynthesis pathway. The FAR activity and relative expression levels of LbaFAR and LbaWSD1 in ‘Ningqi I’ goji were significantly greater than those in ‘Huangguo’ goji. The relative expression levels of these genes significantly increased in the overexpression tobacco lines FAR-OE and WSD1-OE, and the wax load were augmented by 46.10% and 22.23%, respectively. Conclusions The increased expression of the LbaFAR and LbaWSD1 genes in ‘Ningqi I’ leaves led to increased FAR and WSD1 activity, increasing the wax load and alcohol content of the epicuticular of leaves, and improving leaf glossiness, resulting in strengthened resistance to powdery mildew. Therefore, the production of leaf epicuticular wax mediated by the LbaFAR and LbaWSD1 genes could be the main reason for the difference in powdery mildew resistance between the two goji varieties, which can provide a theoretical basis for the selection of resistant varieties to control goji powdery mildew. Graphical Abstract

The Sensitivity of Polar Mesospheric Clouds to Mesospheric Temperature and Water Vapor

Polar mesospheric cloud (PMC) data obtained from the Aeronomy of Ice in the Mesosphere (AIM)/Cloud Imaging and Particle Size (CIPS) experiment and Himawari-8/Advanced Himawari Imager (AHI) observations are analyzed for multi-year climatology and interannual variations. Linkages between PMCs, mesospheric temperature, and water vapor (H2O) are further investigated with data from the Microwave Limb Sounder (MLS). Our analysis shows that PMC onset date and occurrence rate are strongly dependent on the atmospheric environment, i.e., the underlying seasonal behavior of temperature and water vapor. Upper-mesospheric dehydration by PMCs is evident in the MLS water vapor observations. The spatial patterns of the depleted water vapor correspond to the PMC occurrence region over the Arctic and Antarctic during the days after the summer solstice. The year-to-year variabilities in PMC occurrence rates and onset dates are highly correlated with mesospheric temperature and H2O. They show quasi-quadrennial oscillation (QQO) with 4–5-year periods, particularly in the southern hemisphere (SH). The combined influence of mesospheric cooling and the mesospheric H2O increase provides favorable conditions for PMC formation. The global increase in mesospheric H2O during the last decade may explain the increased PMC occurrence in the northern hemisphere (NH). Although mesospheric temperature and H2O exhibit a strong 11-year variation, little solar cycle signatures are found in the PMC occurrence during 2007–2021.

Quantitative aspects of ToF-SIMS analysis of metals and alloys in a UHV, O2 and H2 atmosphere

Although secondary ion mass spectrometry (SIMS) is a versatile method used in the fields of surface analysis, depth profiling and elemental and molecular mapping, it also lacks quantification capabilities. The main reason for this is the matrix effect, which influences the ionization yield of secondary ions with respect to the substrate from which the analyzed compounds originate. There are several approaches to reduce the matrix effect, and gas flooding is one of the easiest methods to apply. In this work, we have investigated the possibilities of the ToF-SIMS method for the quantification of selected metals and alloys containing these metals in different ratios by reducing the matrix effect in the presence of different atmospheres. The measurements were performed in the ultra-high vacuum (UHV) environment, H2 and O2 atmospheres. H2 flooding shows the most significant improvements compared to the UHV analysis, while O2 is also promising but has some limitations. Improvements are most evident for the transition metals Ti, Cr, Fe, Co and Ni employed in our study, while the p-block elements such as Al and Si do not change so extensively. The deviations from the true atomic ratios of selected transition metals in different alloys reach a maximum of only 46 % when analyzed in the H2 atmosphere. In contrast, these values are 66 and 228 % for the O2 atmosphere and UHV environment, respectively. Our results suggest that gas adsorption and consequent formation of a new matrix on the surface, especially in the case of hydrogen, reduces the differences between the different chemical environments and electronic structures of the surface. In this way, the quantitative aspects of the SIMS method can be improved.

Anticorrosion Method Combining Impressed Current Cathodic Protection and Coatings in Marine Atmospheric Environment

In this study, a new anticorrosion method combining impressed current cathodic protection (ICCP) with coatings that can be applied to marine atmospheric environments is proposed. As the corrosion medium fills the cracks and pores of the coating, an electrolyte film layer is inevitably formed on the metal surface. Therefore, a graphene conductive coating with excellent chemical inertness and shielding performance is selected as the intermediate coating to form an electrolytic cell system with a metal substrate serving as the cathode and a graphene coating serving as the auxiliary anode. By studying the surface corrosion morphologies and electrochemical signals of the coating samples at different protection potentials and coating thicknesses, the optimal potential is determined to be 0.6 V, and the optimal coating thickness is determined to be 20 μm. The samples protected by the joint method have lower corrosion rates and better anticorrosion performance than those protected by the coatings alone.

Effects of thermo-oxidative aging on progressive bending damages and electromechanical behaviors of carbon fiber/epoxy 3D woven composites

The effect of thermo-oxidative aging on mechanical properties is important to designing carbon fiber-reinforced composites serviced in long-term atmospheric environments. Here, we report the progressive bending damage behaviors of carbon fiber/epoxy 3D angle-interlock woven composites (3DAWCs) after thermo-oxidative aging. Three-point bending tests were conducted to characterize bending damage behaviors after different aging days. The electrical resistance change of 3DAWCs was also simultaneously measured with the two-probe method during three-point bending tests. Combining side image and digital image correlation (DIC) technology, we found that the bending strength and modulus deteriorated rapidly during thermo-oxidative aging. The strain distribution and progressive bending damage modes also changed significantly, i.e., a symmetrical strain distribution for the unaged specimens, while the existing interface cracks of the aged specimen changed this symmetry. The electrical resistance method (ERM) effectively identified the early-stage damages, and the first derivative of the rate of resistance change (FDC) revealed differences in the progressive damage modes of aged and unaged specimens.

Investigation of the control of Sitophilus granarius in stored grain using vacuum packaging and the creation of an anaerobic atmospheric environment

The efficacy of vacuum and oxygen absorption-based treatments for controlling Sitophilus granarius L. damage in wheat grains was compared under laboratory conditions. The efficacy of the treatments was evaluated at different temperature ranges (−5, 26, 42 °C) and exposure times (0.5, 1, 3, 6, 24, 48, 72 h). Treatment-survived adult progeny were measured on day 45. Our studies demonstrated that the efficacy of the controlled atmosphere methods (CAs) we tested varied significantly as a function of time. While the mortality curve induced by the different temperature-controlled low-pressure vacuum packaging treatments is logarithmic, the mortality trend induced by the absorber's low oxygen levels follows an exponential slope. The hypoxia induced by low oxygen levels has a much longer duration of action. We have shown that vacuum packaging at lower and higher pessimum temperature ranges other than the thermal optimum of the insect induced significant mortality of S. granarius. The method was particularly effective when vacuum-packed items were kept at a higher pessimum temperature range. Our results confirm that vacuum packaging based on atmospheric modification, especially at elevated temperatures, can be a sustainable solution for pest control of small volume, valuable seed samples.

Insights into anthropogenic impact on atmospheric inorganic aerosols in the largest city of the Tibetan Plateau through multidimensional isotope analysis

Particulate inorganic nitrogen aerosols (PIN) significantly influence air pollution and pose health risks worldwide. Despite extensive observations on ammonium (pNH4+) and nitrate (pNO3−) aerosols in various regions, their key sources and mechanisms in the Tibetan Plateau remain poorly understood. To bridge this gap, this study conducted a sampling campaign in Lhasa, the Tibetan Plateau's largest city, with a focus on analyzing the multiple isotopic signatures (δ15N, ∆17O). These isotopes were integrated into a Bayesian mixing model to quantify the source contributions and oxidation pathways for pNH4+ and pNO3−. Our results showed that traffic was the largest contributor to pNH4+ (31.8 %), followed by livestock (25.4 %), waste (21.8 %), and fertilizer (21.0 %), underscoring the impact of vehicular emissions on urban NH3 levels in Lhasa. For pNO3−, coal combustion emerged as the largest contributor (27.3 %), succeeded by biomass burning (26.3 %), traffic emission (25.3 %), and soil emission (21.1 %). In addition, the ∆17O-based model indicated a dominant role of NO2 + OH (52.9 %) in pNO3− production in Lhasa, which was similar to previous observations. However, it should be noted that the NO3 + volatile organic component (VOC) contributed up to 18.5 % to pNO3− production, which was four times higher than the Tibetan Plateau's background regions. Taken together, the multidimensional isotope analysis performed in this study elucidates the pronounced influence of anthropogenic activities on PIN in the atmospheric environment of Lhasa.

Oxygen Impurity-Tuned Structure and Adhesion Properties of the Cu/SiO2 Interface.

The properties of the Cu/SiO2 interface usually deteriorate in the complex atmospheric environment, which may limit its performance and application in the engineering. Using the reactive molecular dynamics method, we investigate how the mechanical behaviors of the Cu/SiO2 interface change as it interacts with oxygen impurities. The interfacial oxidation degree could be enhanced as O2 penetrates into the interface area. This makes the interfacial structure disordered and is not conducive to the survival of Cu-O-Si bondings, which reduces the tensile and shear strengths of the interface. To improve the abrupt bonding property change at the interface and modify the interfacial adhesion properties, O impurities are introduced at the Cu interstitial sites near the interface. By doing so, the interface strength can be significantly enhanced due to the production of typical O-Cu-O bondings while the regular interfacial structure is retained. Meanwhile, the interfacial oxidation also changes the tensile failure site and shearing sliding mode of the interface, i.e., from inside the oxide to between oxide and Cu. The findings of this work may not only advance the understanding of interaction mechanism between oxygen impurities and the Cu/SiO2 interface but also provide new insights into optimizing the bonding properties of the metal/oxide interface.

Assessment of biometeorological conditions in Eastern Mediterranean City Adana, Turkey from past to the future.

Human bioclimatic comfort (HBC) is an important subject of climatology in the field of physical geography. Human bioclimatic comfort (HBC) is the feeling of satisfied and comfortable within the ambient atmospheric thermal environment. Earth climate system has been exposed to changes from the beginning, but since 19th century human - induced factors have contributed to these changes. HBC is the combined effect of atmospheric conditions and affected by all the changes in them. Turkey is among the countries in Mediterranean region, expected to develop higher vulnerabilities to the (bio) climate hazards. Therefore, a Mediterranean city in the south of the country, Adana, was chosen as the study area. HBC assessment was made for the past (1961 - 1990), present (1991 - 2022), near (2030 - 2060) and distant future (2070 - 2100) using hourly - data from the official meteorology station between 1961 and 2022, daily data of the climate model scenarios (Representative Concentration Pathway - RCP4.5 and RCP8.5) and Physiological Equivalent Temperature (PET) index, the Rayman model and Geographic Information Systems in the spatial distribution of HBC conditions. The analysis showed that the prevalence of "cold" and "cool" stresses has decreased while that of "hot" and "very hot" stresses has increased from the past to the present in Adana. It is predicted that present conditions will continue in the near and distant future, all comfort ranges will increase to the following warm range and the ideal period for HBC conditions will be the winter season. In order to reduce the adverse HBC conditions in cities due to climate change by creating climate resilient, sustainable and healthy cities, urban design and planning principles should be followed from a geographical point of view.

Experience reduces route selection for conspecifics by the collectively migrating white stork

Migration can be an energetically costly behavior with strong fitness consequences in terms of mortality and reproduction.1,2,3,4,5,6,7,8,9,10,11 Migrants should select migratory routes to minimize their costs, but both costs and benefits may change with experience.12,13,14 This raises the question of whether experience changes how individuals select their migratory routes. Here, we investigate the effect of age on route selection criteria in a collectively migrating soaring bird, the white stork (Ciconia ciconia). We perform step-selection analysis on a longitudinal dataset tracking 158 white storks over up to 9 years to quantify how they select their routes based on the social and atmospheric environments and to examine how this selection changes with age. We find clear ontogenetic shifts in route selection criteria. Juveniles choose routes that have good atmospheric conditions and high conspecific densities. Yet, as they gain experience, storks' selection on the availability of social information reduces-after their fifth migration, experienced birds also choose routes with low conspecific densities. Thus, our results suggest that as individuals age, they gradually replace information gleaned from other individuals with information gained from experience, allowing them to shift their migration timing and increasing the timescale at which they select their routes.

Transforming stereolithographic prototypes into metal or ceramic models by polymer substitution with titanium powder

The presented paper experimentally demonstrates the potential expansion of stereolithographic prototype utilization. Two methods for manufacturing plastic prototypes are proposed, enabling the subsequent substitution of the polymer material with either metal or ceramics. The first method involves additional actions by the prototype designer during the modeling stage. The second method necessitates alterations in the technological processes of model preparation and prototype manufacturing using a stereolithography apparatus. Material substitution occurs in two stages. Initially, cavities in the prototype are filled with powder material or a mixture of powder and water. Although titanium powder was chosen as the test material, the proposed technology permits the utilization of a broad spectrum of powder materials, encompassing both metallic and ceramic options. The subsequent stage involves heat treatment, where the polymer is eliminated, and the metal powder is sintered while retaining the original shape and dimensions of the prototype. Heat treatment of the acquired prototypes was conducted in both argon and atmospheric air environments. The utilization of different gas media might induce chemical transformations in the material filling the prototype. The experiments lead to the conclusion that the proposed approaches show promise and merit further development. Additionally, we contemplate amalgamating the two methods in the future to attain an optimized final outcome. The data we have gathered could significantly contribute to broadening the scope of stereolithography applications, given that this technology presently represents one of the most precise, widespread, and accessible additive manufacturing methods.